Stabilization of polyolefins with n,n&#39;-tetra-substituted alkylenediamines and oxyalkylenediamines



United States Patent Office 3,418,272 Patented Dec. 24, 1968 3,418,272 STABILIZATION F POLYOLEFINS WITH N,N-

TETRA-SUBSTITUTED ALKYLENEDIAMINES AND OXYALKYLENEDIAMINES Robert M. Pines, Spring Valley, N.Y., assignor to Geigy Chemical Corporation, Greenburgh, N.Y., a corporation of Delaware No Drawing. Continuation of application Ser. No. 208,600, July 9, 1962. This application Dec. 29, 1967, Ser. No. 694,754

6 Claims. (Cl. 260-453) ABSTRACT OF THE DISCLOSURE Compositions of normally solid homopolymers of polyethylene or polypropylene are improved by addition of from about 0.01 to about by weight of N,N-tetrasubstituted alkylenediamines and oxyalkylenediamines of the formula:

wherein R R R R R R and A are as defined in the specification and other stabilizers, particularly hindered phenolic antioxidants. Synergistic combinations of stabilizers of the above formula and phenolic antioxidants are employed in amounts of from about 0.01% to about 10%. A preferred composition exemplified is polypropylene containing 0.1% of bis(2aminoethyl)ether N,N, N,N-tetraacetic acid and 0.1% of 6-(4-hydroxy-3,5-dit-butyl-anilino)-2,4-bis(n-octylthio)-1,3,5-triazine.

THE INVENTION wherein R and R each independently represent hydroxy lower alkyl, especially hydroxymethyl, or carboxy,

R and R each may be carboxy, or when taken in combination with R and R respectively, may be a hydroxy lower alkylene group, especially the Z-hydroxypentylene group to form the cyclohexyl nucleus,

R and R each separately may also be hydrogen,

A may be a lower alkylene group, especially ethylene, a di(lower alkylene) oxy group, especially di(ethylene) oxy, a tri(lower alkylene)dioxy group, e.g. ethyleneoxyethyleneoxyethylene, or the 1,2-cycl0hexylene group.

The mineral acid salts of (I), e.g. the hydrochloric acid salts may be useful, as well as the alkali metal or ammonium salts of I, especially the sodium or potassium salts of I.

While the stabilizers of the Formula I are contemplated for use in polyolefins, it is desirable to use the same not alone, but rather in combination with other thermal and/ or oxidative deterioration inhibiting stabilizer of the Formula I is used in conjunction with such stabilizers there is often observed a synergistic effect in protecting the polyolefin resins against deterioration due to heat and oxidation, as well as the afore-mentioned clarifying effect. Thus, in addition to assisting in the production of a normally solid polyolefin resin of enhanced appearance and color, the stabilizers of the Formula I also remarkable increase the life of the resin as well.

The stabilizers of the Formula I are used generally in an amount of from about 0.01% by weight to about 5% by weight based upon the stabilized composition. Those auxiliary stabilizers which are also present in the resin which is stabilized besides those of the Formula I may be found in amounts from about 0.05% to about 5% by weight in preferred embodiments of the invention.

It has now been found that the stabilizers of Formula I are especially valuable for use in stabilizing polyolefin compositions, e.g. polypropylene or polyethylene, when such stabilizers of the Formula I are used in combination with pigments, coloring agents, light absorbers or other additives, such as thermal and oxidative stabilizers having phenolic groups therein. For example the auxiliary stabilizers of the invention are represented by compounds of the Formula II:

N (II) wherein R and R each independently represent an alkyl group of from 1 to 18 carbon atoms, e.g. methyl, ethyl, propyl, butyl, pentyl, octyl, dodecyl, octadecyl, etc., a cycloalkyl group having 5 or 6 carbon atoms, e.g. cyclopentyl or cyclohexyl, a phenyl group, an alkylphenyl group of from 7 to 24 carbon atoms, e.g. methylphenyl, ethylphenyl, butylphenyl, octylphenyl, octadecylphenyl, dimethylphenyl, dibutylphenyl, dioctadecylphenyl, etc., carbalkoxalkyl of 3 to 15 carbon atoms, e.g. carbomethoxymethyl, carbethoxyethyl, carbobutoxyethyl, carbo-n-lauryloxyethyl, etc. or carbalkoxyphenyl of 8 to 19 carbon atoms, e.g. carbomethoxyphenyl, carbethoxyphenyl, carbo-n-octyloxyphenyl, carbo-n-lauryloxyphenyl, etc., alkylthio-alkyl,

R is defined the same as R and also may be defined as R3,

R represents alkylhydroxyphenyl of 7 to 24 carbon atoms, cg. methylhydroxyphenyl, ethylhydroxyphenyl, butylhydroxyphenyl, octylhydroxyphenyl, octadecylhydroxyphenyl, di-t-butylhydroxyphenyl, methyl-di-tbutylhydroxyphenyl, etc.

X, Y and Z are each independently O, S, imino, substi tuted imino, e.g. benzyl, alkanoyl, lower alkyl, etc. Examples of compounds according to the Formula II which are usefully em loyed in combination with compounds of the Formula I are:

6- 4-hydroxy-3 ,5 -ditbutylanilino -2,4-b is-( n-octylthio)-l,3,5-triazine,

6- (4-hydroxy-3 ,5 -di-t-butylanilino -2,4-bis-phenylthio-l,3,5-triazine,

6- (4hydroxy-3 ,5 -di-t-butylanilino -2,4-bis- (octadecylthio)-l,3,5-triazine,

6-n-octylthio-2,4-bis- (4-hydroxy-3,5-di-t-butylphenoxy) -l ,3,5-triazine,

6- (4 hydroxy-3,S-di-t-butylphenoxy) -2,4-bis- (n-octylthio) -1,3,5-triazine,

6- 4-hydroxy-3,S-di-t-butylphenoxy) -2,4-bis- (n-octylthioethylthio 1,3 ,5 -triazine,

6- (4-hydroxy-3 ,5 -di-t-butylanilino) -2,4-bis-cyclohexylthio-I ,3,5-triazine,

6- (2-hydroxy-3,5-di-t-butyl-6-methylar1ilino) -2,4-bis- (n-octylthio) 1,3,5 -triazine,

6- (4-hydroxy-3 ,5 -di-t-butylanilino) -2,4-bis- 2,3-dimethylphenylthio) 1 ,3 ,5 -tni azine,

6- (4-hydroxy-3,5-di-t-butylanilino -2,4-bis- (carbon-lauryloxyethylthio) 1,3 ,5 -triazine,

6- (4-hydroxy-3,S-di-t-butylanilino) -2,4-bis- (4-t-octylphenoxy) 1 ,3,5-triazine,

6- (4-hydroxy-3,S-di-t-butylanilino -2,4-b is- (Z-carbon-lauryloxyphenylthio) 1,3 ,5 -triazine,

6- (4-hydroxy-3,S-di-t-butyl-N-benzylanilino) -2,4-bisn-octylthio) 1,3,5 -triazine.

Other phenolic stabilizers usefully employed in combination with the stabilizers of the Formula I are those of the Formula I11:

HO R

wherein R is hydroxyl; alkylphenoxy, preferably having from 7 to 24 carbon atoms; phenyl; phenoxy; alkylthio or alkoxy, preferably alkylthio or alkoxy having from 12 to 24 carbon atoms, examples of useful alkoxy groups represented by R being methoxy, ethoxy, isopropoxy, propoxy, butoxy, secondary butoxy, tertiary butoxy, pentoxy, hexoxy, heptoxy, octyloxy, nonyloxy, decyloxy, undecyloxy, dodecyloxy, tridecyloxy, tetradecyloxy, pentadecyloxy, hexadecyloxy, heptadecyloxy, octadecyloxy, nonadecyloxy, heneicosoxy, docosoxy, tricosoxy, tetracosoxy, etc.; in the foregoing examples for R it is understood that oxygen may be usefully substituted by sulfur so that methylthio, ethylthio, isopropylthio, propylthio, butylthio, sec. butylthio, t-butylthio, pentylthio, hexylthio, heptylthio, octylthio, nonylthio, decylthio, dodecylthio, tridecylthio, tetradecylthio, pentadecylthio, undecylthio, hexadecylthio, heptadecylthio, octadecylthio, etc. are also contemplated; examples of useful alkylphenoxy groups represented by R being methylphenoxy, ethylphenoxy, isopropylphenoxy, propylphenoxy, butylphenoxy, dibutylphenoxy, tributylphenoxy, pentylphenoxy, hexylphenoxy, heptylphenoxy, octylphenoxy, nonylphenoxy, decylphenoxy, undecylphenoxy, dodecylphenoxy, tridecylphenoxy, tetradecylphenoxy, pentadecylphenoxy, hexadecylphenoxy, heptadecylphenoxy, octadecylphenoxy, dinonylphenoxy, etc.; alkylthioalkyloxy; alkylthioalkylthio;

R is defined the same as R above, except that R, is not phenyl, nor hydroxyl;

R and R each independently represents alkyl, e.g. alkyl having from 1 to 18 carbon atoms, preferably having from 1 to 5 carbon atoms, especially tertiary butyl; examples of useful alkyl groups being methyl, ethyl, propyl, isopropyl, butyl, secondary butyl, tertiary butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecyl, etc.;

R represents hydrogen or lower alkyl, e.g. methyl, ethyl, propyl, isopropyl, butyl, secondary butyl, tertiary butyl, pentyl, hexyl, but especially methyl; and

n represents 0, 1, 2, or 3 preferably or 1.

In general, it has been found that the stabilizers of the formula I are valuable in enhancing the stabilization effect of a wide variety of stabilizers for polyolefinic material.

This enhancement is surprisingly greater than would be predicted from the stabilization realized by each stabilizer taken alone. Thus, often wherever a stabilizer having a phenolic residue, especially a phenolic residue substituted in at least one of the positions ortho to the phenolic OH group is used in conjunction with a stabilizer of the formula I, a remarkably synergistic stabilizer system is obtained. The foregoing formulae II and III are illustrative of two classes of stabilizers having a phenolic residue therein. The scope of the invention, however, extends beyond these two classes to include any phenolic residue containing stabilizer suitable for the stabilization of polyolefinic material, especially polypropylene. The invention also extends to other stabilizers, such as mercaptoacids of the formula V hereinbelow.

Compounds of the formula II are prepared according to methods described in copending application serial number 81,520, filed February 21, 1961 by M. Dexter et al.

Compounds of the formula III are prepared according to methods described in copending application serial number 102,958, filed April 14, 1961 by J. D. Spivack.

Examples of further phenolic stabilizers are those of the formula IV:

R1 HO O R9 11 (IV) wherein R represents alkylespecially loweralkyl, i.e. having from 1 to 6 carbon atoms, preferably a tertiary butyl group-or hydrogen;

R represents an alkyl group, especially lower alkyl, i.e. having from 1 to 6 carbon atoms, preferably a tertiary butyl group;

A represents an alkylene group (straight or branched chain), preferably lower alkylene having from 1 to 6 carbon atoms, e.g. CH CH CH (oH (OHZ)6-, -CH --CHCH2CHz-, etc.

especially preferred are OH2-, -OH-, (CH2)2 B represents an alkylene group (straight or branched chain), as defined for A above, except that when R is hydrogen in Formula I, then B may contain up to 24 carbon atoms, especially from 6 to 18 carbon atoms;

n represents 1 or 2;

112 represents 0 or 1; and

R represents (a) when n is 1:

(i) hydrogen, or (ii) alkylthioespecially having from 1 to 24 carbon atoms (preferably having from 8 to 18 carbon atoms); or (iii) hydroxyalkylthio-especially hydroxyethylthio; and (b) when n is 2:

(i) alkylenethio, preferably alkylenethio having.

Preparation of the compounds of the Formula IV is disclosed in copending application, Ser. No. 164,618, filed Ian. 5, 1962 by Martin Dexter et al., now abandoned.

Other stabilizers may also be usefully employed in conjunction -with the stabilizers of the Formula I, such as for example stabilizers of the Formula V:

wherein R and R are each independently an alkyl group of from 1 to 24 carbon atoms, such as for example the compound methyl, ethyl, propyl, butyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecylg nonadecyl, eicosyl, heneicosyl, docosyl, tricosyl, tetracosyl. It is a specific object of the invention to provide stabilized compositions of polypropylene and/or polyethylene which are normally solid at room temperature.

It is another object of the invention to provide a method of stabilizing normally solid polypropylene and/ or polyethylene by incorporating therein a minor portion, preferably rom about 0.01% to about (based on the total composition) of a stabilizing system which comprises a stabilizer of the Formula I in an amount of from about 0.01% to about 5% by weight and, in a preferred embodiment, at least one other stabilizer as described above.

Other additives and stabilizers may also be present without adversely affecting the aforesaid stabilizing system.

Solid polymers of polyolefins, e.g. polypropylene, find extensive use in various forms of plastic ware. Many different articles of manufacture are produced from polypropylene plastic materials which can be molded and shaped at higher temperatures While remaining relatively rigid at ordinary room temperature. Polyethylene thermoplastic molding or coating agents have high dielectric strength and excellent resistance to Water, but unfortunately they are prone to attack by atmospheric oxidation and/ or exposure to light, e.g. UV light. Moreover, during processing, such thermoplastic materials are subject to polymeric degradation due to thermal instability. Deterioration caused by one or more of the foregoing may lead to loss, e.g. of dielectric properties, and/or to discoloration, embrittlement or other physical break-down.

The present invention presents a solution to the problem of how to check these deteriorating agencies and enhance the appearance of the solid polypropylene and polyethylene thermoplastic materials so that they may be processed and used in the final product with superior ageing characteristics at both room and elevated temperatures, better color, better processing stability and improved resistance to ultraviolet degradationin short, so that the polypropylene and polyethylene resins employing the stabilizer system of this invention have superior stability characteristics.

While the present stabilizer system employs a compound of Formula I as a basic component, surprisingly in many cases, said system goes far beyond the expected stabilizing power of said compound of Formula I alone. Compositions comprising polypropylene and said compound of Formula I alone, for example, possess far less stability to thermal oxidation than polypropylene resins stabilized with a system according to the present invention compirsing a compound of the Formula I and at least One other stabilizer, e.g. II, III, IV or V. Moreover, the superior results obtained cannot be explained as a mere additive effect. When the system of the invention is employed as a stabilizing system for polypropylene, a surprisingly high increase in ageing life and processing stability at elevated temperatures, is obtained. It is entirely unexpected that the improvement in stability characteristics of the polypropylene is significantly greater than the improvement realized when each of the individual components of the stabilizer system is employed alone under the same conditions. The improvement from the combined stabilizer system is far greater than the sum of the individual improvements due to the single stabilizer components when employed alone in the polypropylene; thus, a true synergism is produced.

Any olefinic polymer, but especially polypropylene and polyethylene, which is normally solid at ordinary room temperature may be stabilized with the system according to the invention.

Thus, besides homopolymeric material, the method of the invention is useful for stabilizing copolymers, including block and graft polymers and physical mixtures thereof.

The stabilizer system of the invention may be incorporated into polypropylene during milling, extruding, or any other suitable process. Moreover, said stabilizer system may be advantageously preformed before incorpora tion into the solid polymer. Alternatively, the individual components of the stabilizer system may be incorporated into the polypropylene separately or in combination with one or several other components. Concentrations of from about 0.01% to about 10% by Weight of the total stabilizer system, based upon the total stabilizer composition, are advantageously employed according to the invention.

In addition to the foregoing auxiliary stabilizers, it is understood that other additives, or coloring agents may be present in the polymeric material to be stabilized. For example, there may be present pigments, dyes, light stabilizers, lubricants, plasticizing agents, anti-slip agents, thermal stabilizers, antioxidants.

Further, the auxiliary stabilizers used in combination with the compounds of the formula I, may be any suit able stabilizer having the group R2 wherein R may be hydrogen or alkyl, especially alkyl from 1 to 12 carbon atoms,

R may be alkyl, especially alkyl having from 1 to 12 carbon atoms; examples of alkyl for R and R being methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, wherein normal or branched chain alkyl groups are contemplated.

Specific auxiliary stabilizers having the group are:

Butylated hydroxyanisole 2,2-thiobis (4-methyl-6-t-butylphenol) 2,2-methylenebis 4-methyl-6-t-butyl phenol) 4,4-butylidenebis(6-t-butylmetacresol) not same as 4,4-thiobis 6-t-butylmetacresol) The following examples of stabilization of polyolefinic material, e.g. polypropylene and polyethylene, are meant for illustration purposes and are not intended to limit the scope of the invention in any Way. In said examples parts are by weight unless otherwise sepcified and the relationship of parts by weight to parts by volume is as that of grams to cubic centimeters. Temperatures are expressed in degrees Centigrade.

Examples: stabilization of polypropylene EXAMPLE 1 Unstabilized polypropylene powder (Hercules Profax 6501) is thoroughly blended with 0.1% by Weight of 7 bis(2-aminoethyl)ether N,N,N;N-tetraacetic acid and 0.1% by weight of 6-(4-hydroxy-3,5-di-t-butylanilino)-2, 4-bis-(n-octylthio)-1,3,5-triazine. The blended material thereafter is milled on a two roller mill at 182 for six minutes, after which time the stabilized polypropylene is sheeted from the mill and allowed to cool.

The milled polypropylene sheet, thus stabilized, is then cut into small pieces and pressed for seven minutes on a hydraulic press at 218 and 174 pounds per square inch pressure. The resultant sheet of 25 mil thickness is then tested for resistance to accelerated aging in a forced draft oven at 149. The stabilized polypropylene is not subject to deterioration after 300 hours in the oven while the unstabilized material deteriorates after about 3 hours; polypropylene stabilized with 0.1% bis(2-aminoethyl)- ether N,N,N',N-tetraacetic acid alone, fails after about 7 hours; polypropylene stabilized with 0.1% of 6-(4-hydroxy-3,S-di-t-butylanilino)-2,4 bis (n-octylthio)-1,3,5- triazine alone fails after 110 hours.

At elevatedtemperatures, for example about 300, the so-stabilized polypropylene exhibits very good processing stability and very little polymer degradation as compared to the unstabilized polypropylene.

If in the foregoing Example 1, the concentrations of the individual stabilizer components each are varied within the stabilizer system so that concentrations of 0.1%, 0.3%, 0.5%, and 1% by Weight, respectively, are employed, then similar results are obtained.

If in the foregoing Example 1, in place of 0.1% of 6-(4-hydroxy-3,S-di-t-butylanilino) -2,4-bis- (n octylthio) 1,3,5-triazine, the same amount of one of the following is substituted:

6- 4-hydroxy-3 ,5 -di-t-butylanilino) -2,4-bis-phenylthio- 1,-3,5-triazine,

6- (4-hydroxy-3 ,5 -di-t-butylanilino) -2,4-bis- (octadecylthio 1, 3 ,5 -triazine,

6- (4-hydroxy-3,S-di-t-butylanilino) -2,4-bis-cyclohexylthio-1,3,5-triazine,

6-(2-hydroxy-3 ,5 -di-t-butyl-6-rnethylanilino) -2,4-bis- (n-octylthio) -1,3,5-triazine,

6- (4-hydroxy-3,S-di-t-butylanilino) -2,4-bis- 2,3-dimethylphenylthio) 1, 3 ,5 -triazine,

6-(4-hydroxy-3 ,5 -di-t-butylanilino) -2,4bis- (carbo-nlauryloxyethylthio) 1,3,5 -triazine,

6- (4-hydr0xy-3 ,5 -di-t-butylanilino) -2,4-bis- (4-t-octylphenoxy) -1,3 ,5 -triazine,

6 (4hydroxy-3,S-di-t-butylanilino) -2,4-bis- (Z-carbo-nlauryloxyphenylthio) -1,3 ,5 -triazine,

6- (4-hydroxy-3,5-di-t-butyl-N-benzylanilino -2,4-bi s- (n-octylthio) -1,3,5-triazine,

2-(n-octylthio -4,6-bis(hydroxy-3,5 -di-t-buty1phenoxy) 1,3,5 -triazine,

then similar results are obtained.

EXAMPLE 2 In the same manner as in Example 1, polypropylene is stabilized with a stabilizer system comprising 0.1% of N-(Z-hydroxyethyl) ethylenediamine N,N,N'-triacetic acid and 0.1% of di-n-octadecyl-3,5-di-t-butyl-4-hydroxybenzylphosphonate (weight percent).

The son-stabilized polypropylene is tested in the same manner as in Example 1 and isstabilized against deterioration for only 300 hours. The unstabilized polypropylene deteriorates after only 3 hours, while when 0.1% by Weight alone of di-n-octadecy1-3,5-di-t-butyl-4-hydroxybenzylphosphonateis used, the stabilization is not effective after 20 hours. Similarly, if 0.1% by weight of N-(2-hydroxyethyl)ethylenediamine N,N',N' triacetic acid alone is used, then the same fails after about 7 hours also.

In a similar way, if instead of 0.1% by Weight of din-octadecyl-3,S-di-t-butyl 4 hydroxybenzylphosphonate one of the following stabilizers is employed in the same amount:

then similar results are obtained.

EXAMPLE 3 In the same manner as in Example 1, stable polypropylene compositions are prepared with 0.1% by Weight of bis(2-aminoethyl)ether N,N,N',N'-tetraacetic acid and 0.1 by weight of each one of the following compounds, taken singly: n-octadecyl-fl-(3,5 di-t-butyl-4-hydroxyphenyl) -propionate, dilauryl-thio-dipropionate.

EXAMPLE 4 In the same manner as in Example 1, stable compositions of polypropylene are prepared with 0.1% by weight of 6-(4-hydroxy-3,S-di-t-butylanilino) 2,4-bis-(n-octylthio)-1,3,5-triazine and 0.1% by Weight of each of the following compounds, taken singly:

Ethylene glycol bis(2-aminoethyl)ether N, N,N,N'-

tetraacetic acid 1,2-diaminocyclohexane N,N,N',N'-tetraacetic acid Ethylenediamine N, N,N',N'-tetraacetic acid N-(Z-hydroxycyclohexyl)ethylenediamine N,N,N',N'-

triacetic acid N,-N-bis (Z-hydroxycyclohexyl)ethylenediamine N,N-

diacetic acid.

What is claimed is:

1. A composition comprising a normally solid homopolyolefin selected from the group of polyethylene and polypropylene, from about 0.05% to about 5% by weight of a stabilizer compound selected from the group of: 6- (4 hydroxy-3,S-di-t-butylanilino) -2,4-bis-(n-octylthio) -1, 3,5-triazine; di-(n-octadecyl) 4 hydroxy-3,5-di-t-butylbenzylphosphonate; n octadecyl ,8-(4-hydroxy-3,5-di-tbutylphenyl)propionate; and 6-n-octylthio-2,4-bis(4-hydroxy-3,S-di-t-butylphenoxy) 1,3,5 triazine; and from about 0.01% to about 5% by weight of a member selected from the group of bis(2-aminoethyl) ether N,N,N',N'-

.tetraacetic acid; ethylene glycol bis(2-aminocthyl) ether N,N,N',N' tetraacetic acid; N-(Z-hydroxycyclohexyl) ethylenediamine N,N',N'-triacetic acid; and N,N-bis(2- hydroxycyclohexyl)ethylenediamine N,N-diacetic acid.

2. A composition comprising a normally solid homopolyolefin selected from the group of polyethylene and polypropylene, from about 0.05% to about 5% by Weight of a stabilizer compound selected from the group of: 6- 4-hydroxy-3,S-di-t-butylanilino) 2,4 bis (n octylthio) -1,3 ,5 -triazine; di- (Ii-octadecyl -4-hydroxy-3,5-di-tbutyl-benzylphosphonate; n-octadecyl ,8-(4-hydroxy-3,5- di-t-butylphenyl)propionate; and 6-n-octylthio-2,4-bis(4- hydroxy-3,5-di-t-butylphenoxy)-1,3,5-triazine, and from about 0.01% to about 5% by Weight of bis(2-aminoethyl) ether N,N,N,N'-tetraacetic acid.

3. A composition comprising a normally solid homopolyolefin selected from the group of polyethylene and polypropylene, from about 0.05% to about 5% by Weight of a stabilizer compound selected from the group of: 6- (4-hydroxy-3,S-di-t-butylanilino) 2,4 bis (n octylthio)-1,3,5-triazine; di-(n-octadecyl) 4 hydroXy-3,5-dit-butyl-benzylphosphonate; n-octadecyl B-(4-hydroxy-3,5- di-t-butylphenyl)propionate; and 6-n-octylthio2,4-bis(4- hydroXy-3,S-di-t-butylphenoxy)-1,3,5-triazine, and from about 0.01% to about 5% by weight of ethylene glycol bis(2-aminoethyl)ether N,N,N,N-tetraacetic acid.

4. A composition comprising a normally solid homopolyolefin selected from the group of polyethylene and polypropylene, from about 0.05% to about 5% by Weight of a stabilizer compound selected from the group of: 6-(4- hydroxy 3,5 di t butylanilino) -2,4-bis-(n-octylthio)- 1,3,5 triazine; di-(n-octadecyl) 4 hydroxy-3,5-di-tbutyl-benzylphosphonate; n-octadecyl-fi-(4-hydroxy 3,5- di-t-butylphenyl)propionate; and 6-n-octylthio-2,4-bis(4- hydroxy-3,S-di-t-butylphenoxy)-l,3,5-triazine, and from about 0.01% to about 5% by weight of 1,2-diaminocyclohexane N,N,N,N-tetraacetic acid.

5. A composition comprising a normally solid homopolyolefin selected from the group of polyethylene and polypropylene, from about 0.05 to about 5% by weight of a stabilizer compound selected from the group of 6-(4- hydroxy 3,5 di t butylanilino)-2-,4-bis-(n-octylthio)-1,3,5-triazine; di-(n-octadecyl) 4 hydroxy-3,5-dit-butyl-benzylphosphonate; n-octadecyl B-(4-hydroxy-3,5- di-t-butylpenyl)propionate and 6-n-octylthio-2,4-bis(4-hydroxy-3,S-di-t-butylphenoxy) 1,3,5 triazine and from about 0.01% to about 5% by Weight of N-(Z-hydroxycyclohexyD-ethylenedamine N,N,N'-triacetic acid.

6. A composition comprising a normally solid homopolyolefin selected from the group of polyethylene and polypropylene and from about 0.05% to about 5% by weight of a stabilizer compound selected from the group of 6 (4 hydroxy-S,S-di-t-butylanilino)-2,4-bis-(n-octylthio) 1,3,5 triazine; di-(n-octadecyl)-4-hydroXy-3,5- di-t-butyl-benzylphosphonate; n-octadecyl fi-(4-hydroxy- 3,5-di-t-butylphenyl)propionate and 6-n-octylthio-2,4-bis (4-hydroxy-3,S-di-t-butylphenoxy)1,3,5-triazine and from about 0.01% to about 5% by weight of N,N'-bis(2-hydroxycyclohexyl)ethylenediamine N,N-diacetic acid.

References Cited UNITED STATES PATENTS 2,667,522 1/1954 McElroy 26045.9 2,878,232 3/1959 Schweitzer 26045.9 2,994,675 8/1961 Haward et al. 260--45.9 3,017,422 1/1962 Thompson 26045.95 3,255,191 6/1966 Dexter et al 26045.8 3,280,070 10/1966 DiBattista et al. 26045.85 2,428,353 10/ 1947 Bersworth 26045.85 3,033,814 5/1962 Tholstrup 26045.95 3,065,200 11/1962 Johansson 26045.9 2,829,121 4/1958 Leeper 26045.9 3,068,197 12/1962 Rocklin 26045.85

FOREIGN PATENTS 1,190,714 10/1959 France.

DONALD E. CZAJA, Primary Examiner. H. TAYLOR, Assistant Examiner.

US. Cl. X.R.

UNITED STATES PATENT OFFICE CERTIFICATE OF CORRECTION Patent No. 3,418,272 December 24, 1968 Robert M. Pines It is certified that error appears in the above identified patent and that said Letters Patent are hereby corrected as shown below: Column 2, line 7, "bilizer of the Formula I is used in conjunction with such" should read bilizers. When a stabilize of the Formula I is used in conjunction with such line 14, "remarkable" should read remarkably Column 4, lines 24 to 3D, the right-hand portion of the formula reading "-B shoulc read R Column 5, line 26, "rom" should read from Column 6, line 61, cancel "not same as". Column 8, line 44, "N,N,N ;N" should read N, N,N Column 9 line 30 "butylp'enyl" should read butylphenyl Signed and sealed this 17th day of March 1970.

(SEAL) Attest:

Edward M. Fletcher, Jr. E.

Attesting Officer Commissioner of Patents 

